Metal‐Free SF <sub>6</sub> Activation: A New SF <sub>5</sub> ‐Based Reagent Enables Deoxyfluorination and Pentafluorosulfanylation Reactions

نویسندگان

چکیده

The activation of SF6, a potent greenhouse gas, under metal-free and visible light conditions is reported. Herein, mechanistic investigations including EPR spectroscopy, NMR studies cyclic voltammetry allowed the rational design new fluorinating reagent which was synthesized from 2-electron SF6 with commercially available TDAE. This SF5-based efficiently employed for deoxyfluorination CO2 fluorinative desulfurization CS2 allowing formation useful fluorinated amines. Moreover, first time we demonstrated that our could afford mild generation Cl-SF5 gas. finding exploited chloro-pentafluorosulfanylation alkynes alkenes.

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2022

ISSN: ['1521-3773', '1433-7851', '0570-0833']

DOI: https://doi.org/10.1002/ange.202204623